An unprecedented use for glycerol: chemoselective reducing agent for sulfoxides

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An Unprecedented Use for Glycerol: Chemoselective Reducing Agent for Sulfoxides†

A new application for glycerol that expands its possibilities apart from green solvent and precursor of value-added products has been demonstrated. Simple, easily available, and environmentally friendly dioxomolybdenum(VI) complexes are highly efficient catalysts for the chemoselective sulfoxide deoxygenation with this biomass-derived chemical feedstock. Both refined glycerol and crude glycerin 10

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Pinacol as a New Green Reducing Agent: Molybdenum- Catalyzed Chemoselective Reduction of Sulfoxides and Nitroaromatics

Pinacol is described as a new chemoselective and environmentally benign reducing agent for sulfoxides and nitroaromatics assisted by readily available dichlorodioxomolybdenum(VI) complexes as catalysts. A wide range of substrates including those bearing challenging functional groups have been efficiently and selectively reduced being acetone and water the only byproducts of these reactions.

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ژورنال

عنوان ژورنال: Green Chemistry

سال: 2013

ISSN: 1463-9262,1463-9270

DOI: 10.1039/c3gc36908k